Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I)
نویسندگان
چکیده
The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is almost planar, the maximum deviation from the mol-ecular plane being 0.48 (4) Å. The coordination environment of the Cu(2+) ion is distorted square-planar and it is N(2)O(2)-chelated by the Schiff base ligand. The Na(+) cation has a distorted octahedral environment defined by the four O atoms of the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand, a water ligand and a dicyanamide anion.
منابع مشابه
Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium
The mol-ecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is approximately planar, with a maximum deviation from the mol-ecular plane of 0.770 (5) Å. The coordination environment of the Ni(2+) ion is distorted square-planar and it is N(2)O(2) coordinated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na(+) atom i...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 6,O 1,O 1′,O 6′:2κ4 O 1,N,N′,O 1′}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I)
The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar with mean deviation of 5.2 (8)°. The coordination environment of the Cu(II) ion is distorted square-planar and it is N(2)O(2)-chelated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff bas...
متن کاملAqua{4,4′-dibromo-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
The title complex, [Cu(C(18)H(16)Br(2)N(2)O(4))(H(2)O)], lies on a crystallographic mirror plane with the Cu(II) ion coordinated by two N atoms and two O atoms of a tetra-dentate Schiff base ligand and one O atom from a water ligand in a slightly distorted square-pyramidal environment. The mirror plane, which coincides with the Cu-O(water) bond, imposes disorder of the atoms of the ethyl-ene gr...
متن کاملAqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III)
The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxy-salicylaldehyde in presence of manganese(II) 4-hydroxy-benzoate. The Jahn-Teller-distorted manganese(III) centre has an octa-hedral geometry. Extensive O-H⋯O hydrogen-bonding inter-actions generate a two-dimensional sheet structure parallel to (103).
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoholmium(III)zinc(II)
In the title heteronuclear Zn(II)-Ho(III) complex (systematic name: {μ-6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κ(4)O(1),O(1'),O(6),O(6'):2κ(4)O(1),N,N',O(1'))-μ-nitrato-1:2κ(2)O:O'-dinitrato-1κ(4)O,O'-holmium(III)zinc(II)), [HoZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-ened...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009